Ted Sargents Lab

Left to proper: Adnan Ozden, Joshua Wicks, and F. Pelayo García de Arquer are among the many staff members who’ve designed an electrolyzer that converts CO2 to helpful merchandise 10 occasions sooner than earlier variations. Credit score: U of T Engineering / Daria Perevezentsev

Researchers develop enhanced machine to remodel CO2 into helpful chemical compounds 10 occasions sooner than earlier variations.

Gas cells flip chemical compounds into electrical energy. Now, a College of Toronto Engineering staff has tailored expertise from gasoline cells to do the reverse: harness electrical energy to make helpful chemical compounds from waste carbon (CO2).

“For many years, proficient researchers have been growing techniques that convert electrical energy into hydrogen and again once more,” says Professor Ted Sargent (ECE), one of many senior authors of a paper revealed in Science on February 7, 2020.  “Our innovation builds on that legacy, however by utilizing carbon-based molecules, we are able to plug straight into present hydrocarbon infrastructure.”

In a hydrogen gasoline cell, hydrogen and oxygen come collectively on the floor of a catalyst. The chemical response releases electrons, that are captured by specialised supplies inside the gasoline cell and pumped right into a circuit.

The other of a gasoline cell is an electrolyzer, which makes use of electrical energy to drive a chemical response. The brand new paper’s authors are consultants in designing electrolyzers that convert CO2 into different carbon-based molecules, comparable to ethylene. The staff contains MIE PhD candidate Adnan Ozden, who’s supervised by Professor David Sinton (MIE), in addition to a number of members of Sargent’s staff, together with ECE PhD candidate Joshua Wicks, ECE postdoctoral fellow F. Pelayo García de Arquer and former ECE postdoctoral fellow Cao-Thang Dinh.

Ted Sargents Lab

Left to proper: Adnan Ozden, Joshua Wicks, and F. Pelayo García de Arquer are among the many staff members who’ve designed an electrolyzer that converts CO2 to helpful merchandise 10 occasions sooner than earlier variations. Credit score: U of T Engineering / Daria Perevezentsev

“Ethylene is likely one of the most generally produced chemical compounds on the earth,” says Wicks. “It’s used to make the whole lot from antifreeze to garden furnishings. At this time it’s derived from fossil fuels, but when we might as a substitute make it by upgrading waste CO2, it could present a brand new financial incentive for capturing carbon.”

At this time’s electrolyzers don’t but produce ethylene on a scale giant sufficient to compete with what’s derived from fossil fuels. A part of the problem lies within the distinctive nature of the chemical response that transforms CO2 into ethylene and different carbon-based molecules.

“The response requires three issues: CO2, which is a fuel; hydrogen ions, which come from liquid water; and electrons, that are transmitted via a steel catalyst,” says Ozden. “Bringing these three totally different phases — particularly the CO2 — collectively rapidly is difficult, and that’s what has restricted the speed of the response.”

Of their newest electrolyzer design, the staff used a singular association of supplies to beat the challenges of bringing the reactants collectively. Electrons are delivered utilizing a copper-based catalyst that the staff had beforehand developed. However as a substitute of a flat sheet of steel, the catalyst within the new electrolyzer is within the type of small particles embedded inside a layer of a fabric generally known as Nafion.

Nafion is an ionomer — a polymer that may conduct charged particles generally known as ions. At this time, it’s generally utilized in gasoline cells, the place its position is to move positively charged hydrogen (H+) ions round inside the reactor.

“In our experiments, we found sure association of Nafion can facilitate the transport of gases comparable to CO2,” says García de Arquer. “Our design permits fuel reactants to succeed in the catalyst floor quick sufficient and in a sufficiently distributed method to considerably enhance the speed of response.”

With the response not restricted by how rapidly the three reactants can come collectively, the staff was capable of rework CO2 into ethylene and different merchandise 10 occasions sooner than earlier than. They achieved this with out lowering the general effectivity of the reactor, that means extra product for roughly the identical capital price.

Regardless of the advance, the machine stays a great distance from business viability. One of many main remaining challenges has to do with the steadiness of the catalyst beneath the brand new higher-current densities.

“We are able to pump in electrons 10 occasions sooner, which is nice, however we are able to solely function the system for about ten hours earlier than the catalyst layer breaks down,” says Dinh. “That is nonetheless removed from the goal of hundreds of hours that will be wanted for industrial software.”

Dinh, who’s now a professor of chemical engineering at Queen’s College, is continuous the work by wanting into new methods for stabilizing the catalyst layer, comparable to additional modifying the chemical construction of the Nafion or including further layers to guard it.

The opposite staff members plan to work on totally different challenges, comparable to optimizing the catalyst to provide different commercially helpful merchandise past ethylene.

“We picked ethylene for example, however the ideas right here may be utilized to the synthesis of different helpful chemical compounds, together with ethanol” says Wicks. “Along with its many industrial makes use of, ethanol can be broadly used as a gasoline.”

The power to provide fuels, constructing supplies, and different merchandise in a carbon-neutral approach is a crucial step in direction of lowering our dependence on fossil fuels.

“Even when we cease utilizing oil for power, we’re nonetheless going to wish all of those molecules,” says García de Arquer. “If we are able to produce them utilizing waste CO2 and renewable power, we are able to have a significant impression when it comes to decarbonizing our economic system.”

Reference: “CO2 electrolysis to multicarbon merchandise at actions larger than 1 A cm−2” by F. Pelayo García de Arquer, Cao-Thang Dinh, Adnan Ozden, Joshua Wicks, Christopher McCallum, Ahmad R. Kirmani, Dae-Hyun Nam, Christine Gabardo, Ali Seifitokaldani, Xue Wang, Yuguang C. Li, Fengwang Li, Jonathan Edwards, Lee J. Richter, Steven J. Thorpe, David Sinton and Edward H. Sargent, 7 February 2020, Science.
DOI: 10.1126/science.aay4217


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